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31.
在甲醇溶液中合成了一系列IIB过渡金属Zn(II), Cd(II)的二羟乙基二硫代氨基甲酸[(EtOH)2dtc]的配合物, 并对配合物M[(EtOH)2dtc]2L [M=Zn (1), Cd (2), L=2,2'-联吡啶; M=Zn (3), Cd (4), L=邻菲啰啉]进行了红外光谱、元素分析、热重分析表征工作. 热重分析表明配合物1~4中DTC配体比中性配体更易失去, 热分解最终产物为相应的氧化物. 对化合物1, 2做了X-ray单晶衍射分析, 1为单斜晶系, P21/c空间群, 晶胞参数a=0.72146(5) nm, b=2.61720(18) nm, c=1.59438(11) nm,b=97.899(2)°, V=2.9820(4) nm3, Z=4, m=1.133 mm-1, Dc=1.297 Mg•m-3; 2为三斜晶系, P-1空间群, 晶胞参数a=1.0075(2) nm, b=1.1580(2) nm, c=1.1777(2) nm, a=70.92(3)°, b=85.71(3)°, γ=81.02(3)°, V=1.2822(4) nm3, Z=2, m=2.118 mm-1, Dc=1.630 Mg•m-3. 相似文献
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Four para-dialkylaminophenyl (PDAAP1-PDAAP4) bearing carboxyl groups were studied for application to the dye-sensitized solar cells (DSC). It was found the short spacer CH2 between carboxyl and dialkylaminophenyl chromophore in PDAAP3 and PDAAP4 led to highly efficient monochromatic incident photon-to-current conversion efficiencies (IPCE), however the long alkyl group C4H9 attached on aniline moieties in PDAAP2 and PDAAP4 favored improvement of open-circuit photovoltage. Thus, the solar cell sensitized by PDAAP4, having both short carboxyl groups CH2COOH and long alkyl groups C4H9, exhibited the IPCE maximum of 73% at 670 nm and overall energy conversion efficiency η of 3.06%, representing the highest IPCE and η values so far in dialkylaminophenyl-based organic dye-sensitized semiconductor solar cells. Taking advantage of the highly efficient sensitizing ability of PDAAP4 in far-red region, the data of IPCE above 630 nm of the solar cells were improved greatly by cosensitization with both N3 and PDAAP4. The influences of the TiO2 film thickness and the concentration of 4-tert-butylpyridine (TBP) in electrolyte were also investigated. 相似文献
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A thin film of manganese hexacyanoferrate (MnHCF) was electrochemically formed on a glassy carbon (GC) electrode to prepare a chemically modified electrode (CME). The mechanism of film formation of MnHCF and its growth process were investigated in detail by cyclic voltammetry. The results show that the stoichiometric composition of MnHCF is Mn^ⅢFe^Ⅲ(CN)6, an analogue of prussian yellow. There exist three clear-cut stages in the whole modification process and the last stage is indispensable to the fabrication of homogenized, stable MnHCF film and must last for an appropriate time. The surface morphology of MnHCF/GC electrode was characterized by scanning electron microscopy (SEM), which further verified the effective deposition of MnHCF film on GC. The kinetic constants of MnHCF/GC electrode process were also evaluated. The resulting MnHCF film modified electrode presented good stability and high electrocatalytic activity toward the oxidation of H2O2, indicating that MnHCF film possesses function of catalase and can be expected for analytical purposes. 相似文献
36.
红外光谱法研究LB膜中的分子取向 总被引:1,自引:0,他引:1
The structure information of orientation and packing of molecular chains can be obtained from infrared transmission and reflection-absorbance (RA) spectra. In the present paper, on the basis of Umemura et al., their FORTRAN program of minicomputer was developed and can be run on 486 personal computer. By comparison of infrared transmission and RA intensities, surface enhancement factors and molecular orientation angle were calculated using the above program, and the influence of complex refractive index, angle of incidence, and thickness of LB film were discussed. These results are consistent with that of Umemura et al. 相似文献
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高稳定性CaO-ZrO2固体碱催化剂的表征和催化性能 总被引:3,自引:0,他引:3
用共沉淀法经高温焙烧制备了CaO摩尔分数从10%至50%的CaO-ZrO2系列催化剂, 将其应用于碳酸丙烯酯和甲醇酯交换合成碳酸二甲酯过程, 并通过XRD, FT-IR, BET, ICP, CO2-TPD, XPS等表征手段研究了催化剂的物性及其催化性能随组成变化的的规律. 结果表明, 当CaO摩尔分数高于30%时, 表面出现游离的CaO, 虽然具有强碱性和高活性, 但是稳定性差; 而当CaO摩尔分数低于30%时, Ca2+进入ZrO2晶格, CaO与ZrO2形成连续固溶体, 并且随着CaO含量的增加, 晶格氧的电荷密度增加, 催化剂的碱性增强, 使得CaO-ZrO2催化剂在碳酸丙烯酯和甲醇酯交换合成碳酸二甲酯过程中获得了高活性和高稳定性. 相似文献
39.
4,4'-联吡啶与二苄基二硫代氨基甲酸镉配合物[Cd(DBTC)2]2 (1)反应得到加合物[Cd(DBTC)2(4,4'-bipy)] (2) (DBTC=N,N-二苄基二硫代氨基甲酸), 通过晶体结构分析及红外光谱等研究其结构与性质. 结果表明: 引入小分子配体会破坏[Cd(DBTC)2]2 (1)的二聚结构, 加入吡啶则得到单核的吡啶加合物[Cd(DBTC)2py] (3), 而引入4,4'-联吡啶后其结构变为新型的一维链状结构的配位聚合物2, 这种结构在二硫代氨基甲酸金属配合物中少见报道. 也比较了不同配体如吡啶及4,4'-联吡啶对Cd(II)及Zn(II)配合物结构的影响. 相似文献
40.
用溶剂热方法合成了[Me4N]2HgGe4S10, 通过单晶X射线衍射, IR, DSC-TG手段对其进行了表征. 结果表明, 标题化合物属四方晶系, I-4空间群, 晶胞参数a=0.92687(8) nm, c=1.43739(12) nm, V=1.23484(18) nm3, Z=2, Mo Kα λ=0.071073 nm, R1=0.0570, wR2=0.1374, 空旷骨架结构由超四面体Ge4S10与HgS4四面体共用顶点连接而成, 有机模板离子在一维孔道中. 该化合物具有一定的热稳定性, 在320 ℃发生分解形成GeS2. 相似文献